三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

邢宇博; 劉宇奇; 王新穎; 薛曉斐; 李瑋

doi:10.7540/j.ynu.20160746

三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

1.
昆明理工大學理學院,云南昆明 650500

作者簡介: 邢宇博(1991-),男,山西人,碩士生.主要從事功能配合物的研究.Email:xingyb2015@163.com.;

通訊作者: 劉宇奇, liuyuqi7547@163.com ;

基金項目:
云南省中青年學術技術帶頭人后備人才項目(2011CI010)

昆明理工大學引進人才科研啟動基金(KKSY201507026)

昆明理工大學分析測試基金(20150633)
中圖分類號: O611.4

Hydrothermal synthesis,crystal structure and magnetic property of a 3D coordinated complex {[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n

1.
Faculty of Science,Kunming University of Science and Technology,Kunming 650500,China

Corresponding author: LIU Yu-qi, liuyuqi7547@163.com ;

CLC number: O611.4

摘要: 采用水熱法合成出一種新型金屬有機功能配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n(C12H6O4為去質子化的1,4-萘二甲酸,(C11H18N4)2+為質子化的1,1'-(1,5-戊烷基)二咪唑).通過X射線單晶衍射技術對該化合物進行結構表征,結果表明該化合物屬于單斜晶系C2/c空間群,其晶胞參數分別為a=1.19795(4)nm,b=2.76457(10)nm,c=1.56451(5)nm,α=90°,β=9.37290(10)°,γ=90°,Z=4,V=5.1704(3)nm3,F(000)=2508.錳離子以六配位的方式與6個1,4-萘二甲酸中的氧原子結合形成扭曲的八面體構型.C11H18N4分子以游離形式存在于體系中,一方面質子化后起到平衡電荷的作用;另一方面與1,4-萘二甲酸羰基氧原子形成豐富的氫鍵作用力.有機配體1,4-萘二甲酸以不同的配位模式連接中心錳原子,最終使配合物形成了一個具有網狀結構的三維配位聚合物.磁學性質研究表明:該配合物存在弱的反鐵磁性,線性擬合得到配合物的居里外斯溫度T=-16.265197K.CCDC:1517397.
- 金屬有機功能配合物 /
- 晶體結構 /
- 1 /
- 4-萘二甲酸 /
- 磁學性質
Abstract: A new manganese coordination polymer,{[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n (C12H6O4 was deprotonated 1,4-naphthalene dicarboxylic acid;C11H18N4 was protonated 1,1-(1,5-pentanedidyl)bis(imidazole))has been synthesized hydrothermally.X-ray crystal structural dates reveal that the compound crystallizes in monoclinic space groups C2/c.The cell parameters are as follows:a=1.19795(4)nm,b=2.76457(10)nm,c=1.56451(5)nm,α=90°,β=9.37290(10)°,γ=90°,Z=4,V=5.1704(3)nm3,F(000)=2508.Each Mn(Ⅱ) ion is hexa-coordinated by six O atoms from six 1,4-naphthalene dicarboxylic acids,forming octahedral coordination geometry with slight distortion.The C11H18N4 ligand in complex is completely protonated which could not only balance the electric charge of metal ions in the whole framework,but also interlink the carbonyl O atoms of 1,4-naphthalene dicarboxylic acid through hydrogen bonds.The carboxylate oxygen atoms of C12H6O4 are coordinated to Mn(Ⅱ) ions in two different modes,resulting into 3D polycatenation frameworks.The magnetic property of the complex was also investigated and the magnetic susceptibility datas were rationally fitted with T=-16.265197K.showing weakly antiferromagnetic interactions among Mn(Ⅱ) ions in the complex.CCDC:1517397.
- metal-organic frameworks /
- crystal structure /
- 1 /
- 4-naphthalene dicarboxylic acid /
- magnetism

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三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

作者簡介: 邢宇博(1991-),男,山西人,碩士生.主要從事功能配合物的研究.Email:xingyb2015@163.com.;

通訊作者: 劉宇奇, liuyuqi7547@163.com ;

Hydrothermal synthesis,crystal structure and magnetic property of a 3D coordinated complex {[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n

Corresponding author: LIU Yu-qi, liuyuqi7547@163.com ;

計量

三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

作者簡介:邢宇博(1991-),男,山西人,碩士生.主要從事功能配合物的研究.Email:xingyb2015@163.com.

通訊作者: 劉宇奇, liuyuqi7547@163.com;

English Abstract

Hydrothermal synthesis,crystal structure and magnetic property of a 3D coordinated complex {[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n

Corresponding author: LIU Yu-qi, liuyuqi7547@163.com

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三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

作者簡介: 邢宇博(1991-),男,山西人,碩士生.主要從事功能配合物的研究.Email:xingyb2015@163.com.;

通訊作者: 劉宇奇, liuyuqi7547@163.com ;

Hydrothermal synthesis,crystal structure and magnetic property of a 3D coordinated complex {[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n

Corresponding author: LIU Yu-qi, liuyuqi7547@163.com ;

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三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

作者簡介:邢宇博(1991-),男,山西人,碩士生.主要從事功能配合物的研究.Email:xingyb2015@163.com.

通訊作者: 劉宇奇, liuyuqi7547@163.com;

English Abstract

Hydrothermal synthesis,crystal structure and magnetic property of a 3D coordinated complex {[Mn3(C12H6O4)4]2-·(C11H18N4)2+}n

Corresponding author: LIU Yu-qi, liuyuqi7547@163.com

全文HTML

目錄

三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究

三維配合物{[Mn3(C12H6O4)4]2-(C11H18N4)2+}n的水熱合成、晶體結構和磁性研究